1,8-cineole synthase EC#: 4.2.3.108; ChemWhat Code: 1382689
| Product Name | 1,8-cineole synthase |
| Example Structure |  |
| Synonyms | 1,8-cineole cyclase; geranyl pyrophoshate:1,8-cineole cyclase, 1,8-cineole synthetase, AaTPS6, CIN, CinS, leucoplast 1,8-cineole synthase, LnTPS1, plastid terpineol synthase, SabS1, SCLAV_p0982, SSCG_00536, SSS, TER, TPS1, TPS6 |
| EC Number | 4.2.3.108 |
| CAS Registry Number | |
| Comments | Requires Mn2+?or Zn2+. Mg2+?is less effective than either. 1,8-Cineole is the main product from the enzyme with just traces of other monoterpenoids. The oxygen atom is derived from water. The reaction proceeds via linalyl diphosphate and ¦Á-terpineol, the stereochemistry of both depends on the organism. However neither intermediate can substitute for geranyl diphosphate. The reaction in?Salvia officinalis?(sage) proceeds via (?)-(3R)-linalyl diphosphate [1-3] while that in Arabidopsis (rock cress) proceeds via (+)-(3S)-linalyl diphosphate [4]. |
| Cofactor | Zn2+?or?Mn2+ |
| History | |
| Reactions | Geranyl diphosphate + H(2)O = 1,8-cineole + diphosphate. |
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