2-hydroxyethylphosphonate dioxygenase EC#: 1.13.11.72; ChemWhat Code: 1375002

Product Name 2-hydroxyethylphosphonate dioxygenase
Example Structure Example Structure of 2-hydroxyethylphosphonate dioxygenase EC#: 1.13.11.72
Synonyms HEPD, PhdP, phpD
EC Number 1.13.11.72
CAS Registry Number
Comments Requires non-heme-Fe(II). Isolated from some bacteria including Streptomyces hygroscopicus and Streptomyces viridochromogenes. The pro-R hydrogen at C-2 of the ethyl group is retained by the formate ion. Any stereochemistry at C-1 of the ethyl group is lost. One atom from dioxygen is present in each product. Involved in phosphinothricin biosynthesis.
Cofactor Fe cation
History
Reactions 2-hydroxyethylphosphonate + O(2) = hydroxymethylphosphonate + formate.

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