2-methylcitrate dehydratase (2-methyl-trans-aconitate forming) EC#: 4.2.1.117; ChemWhat Code: 1382417
| Product Name | 2-methylcitrate dehydratase (2-methyl-trans-aconitate forming) |
| Example Structure |  |
| Synonyms | AcnD, SO_0343 |
| EC Number | 4.2.1.117 |
| CAS Registry Number | |
| Comments | Catalyses the dehydration of (2S,3S)-2-methylcitrate, forming the?trans?isomer of 2-methyl-aconitate (unlike EC?4.2.1.79, which forms only the?cis?isomer). Part of a propionate degradation pathway. The enzyme from?Shewanella oneidensis?can also accept citrate and?cis-aconitate, but activity with (2S,3S)-2-methylcitrate was approximately 2.5-fold higher. 2-methylisocitrate and isocitrate were not substrates [1]. An iron-sulfur protein. |
| Cofactor | iron-sulfur |
| History | |
| Reactions | (2S,3S)-2-methylcitrate = 2-methyl-trans-aconitate + H(2)O. |
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