2,5-diketocamphane 1,2-monooxygenase EC#: 1.14.14.108; ChemWhat Code: 1375616
| Product Name | 2,5-diketocamphane 1,2-monooxygenase |
| Example Structure |  |
| Synonyms | 2,5-diketocamphane 1,2-monooxygenase, 2,5-diketocamphane lactonizing enzyme, 2,5-diketocamphane monooxygenases, 2,5-DKCMO, 2,5-DKCMO-1, 2,5-DKCMO-2, 3,6-diketocamphane 1,6-monooxygenase, camE25-1, camE25-2, camphor ketolactonase I, ketolactonase I, More, oxygenase, camphor 1,2-mono |
| EC Number | 1.14.14.108 |
| CAS Registry Number | |
| Comments | A Baeyer-Villiger monooxygenase isolated from camphor-grown strains of Pseudomonas putida and encoded on the cam plasmid. Involved in the degradation of (+)-camphor. Requires a dedicated NADH-FMN reductase [cf. EC 1.5.1.42, FMN reductase (NADH)] [1-3]. Can accept several bicyclic ketones including (+)- and (?)-camphor [6] and adamantanone [4]. The product spontaneously converts to [(1R)-2,2,3-trimethyl-5-oxocyclopent-3-enyl]acetate. |
| Cofactor | Fe cation |
| History | |
| Reactions |
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