3-hydroxy-1,2-didehydro-2,3-dihydrotabersonine reductase EC#: 1.1.99.41; ChemWhat Code: 1373720

Product Name 3-hydroxy-1,2-didehydro-2,3-dihydrotabersonine reductase
Example Structure Example Structure of 3-hydroxy-1,2-didehydro-2,3-dihydrotabersonine reductase EC#: 1.1.99.41
Synonyms ADHL1, BARS1, T3R, tabersonine 3-reductas, tabersonine 3-reductase
EC Number 1.1.99.41
CAS Registry Number
Comments This enzyme is involved in the biosynthesis of vindoline and vindorosine in the plant Catharanthus roseus (Madagascar periwinkle). In vivo, it functions in the direction of reduction. It has no activity with 3-epoxylated compounds, which can form spontaneously from its unstable substrates.
Cofactor
History
Reactions (1) (3R)-3-hydroxy-16-methoxy-2,3-dihydrotabersonine + acceptor = (3R)-3- hydroxy-16-methoxy-1,2-didehydro-2,3-dihydrotabersonine + reduced acceptor. (2) (3R)-3-hydroxy-2,3-dihydrotabersonine + acceptor = (3R)-3-hydroxy- 1,2-didehydro-2,3-dihydrotabersonine + reduced acceptor.

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