3,5-dihydroxybiphenyl synthase EC#: 2.3.1.177; ChemWhat Code: 1376978

Product Name 3,5-dihydroxybiphenyl synthase
Example Structure Example Structure of 3,5-dihydroxybiphenyl synthase EC#: 2.3.1.177
Synonyms biphenyl synthase, BIS, BIS1, BIS2, BIS3, BIS4
EC Number 2.3.1.177
CAS Registry Number 1217551-24-0
Comments A polyketide synthase that is involved in the production of the phytoalexin aucuparin. 2-Hydroxybenzoyl-CoA can also act as substrate but it leads to the derailment product 4-hydroxycoumarin (cf. EC 2.3.1.208, 4-hydroxycoumarin synthase) [2]. This enzyme uses the same starter substrate as EC 2.3.1.151, benzophenone synthase.
Cofactor
History
Reactions 3 malonyl-CoA + benzoyl-CoA = 4 CoA + 3,5-dihydroxybiphenyl + 4 CO(2).

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