3,5,7-trioxododecanoyl-CoA synthase EC#: 2.3.1.206; ChemWhat Code: 1377020

Product Name 3,5,7-trioxododecanoyl-CoA synthase
Example Structure Example Structure of 3,5,7-trioxododecanoyl-CoA synthase EC#: 2.3.1.206
Synonyms olivetol synthase, olivetol-forming PKS, OLS, PKS, polyketide synthase, tetraketide synthase, TKS, type III PKS, type III polyketide synthase
EC Number 2.3.1.206
CAS Registry Number
Comments A polyketide synthase catalysing the first committed step in the cannabinoids biosynthetic pathway of the plant Cannabis sativa. The enzyme was previously thought to also function as a cyclase, but the cyclization is now known to be catalysed by EC 4.4.1.26, olivetolic acid cyclase.
Cofactor
History
Reactions 3 malonyl-CoA + hexanoyl-CoA = 3 CoA + 3,5,7-trioxododecanoyl-CoA + 3 CO(2).

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