4-hydroxyacetophenone monooxygenase EC#: 1.14.13.84; ChemWhat Code: 1375309

Product Name 4-hydroxyacetophenone monooxygenase
Example Structure Example Structure of 4-hydroxyacetophenone monooxygenase EC#: 1.14.13.84
Synonyms 4-hydroxyacetophenone monooxygenase, arylketone monooxygenase, Baeyer-Villiger monooxygenase, hAPA, HAPMO, More, oxygenase, 4-hydroxyacetophenone mono-
EC Number 1.14.13.84
CAS Registry Number
Comments Contains FAD. The enzyme from Pseudomonas fluorescens ACB catalyses the conversion of a wide range of acetophenone derivatives. Highest activity occurs with compounds bearing an electron-donating substituent at the para position of the aromatic ring [1]. In the absence of substrate, the enzyme can act as an NADPH oxidase (EC 1.6.3.1).
Cofactor FAD
History
Reactions (4-hydroxyphenyl)ethan-1-one + Nadph + O(2) = 4-hydroxyphenyl acetate + NADP(+) + H(2)O.

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