6-oxocamphor hydrolase EC#: 3.7.1.18; ChemWhat Code: 1381799

Product Name 6-oxocamphor hydrolase
Example Structure Example Structure of 6-oxocamphor hydrolase EC#: 3.7.1.18
Synonyms 6-oxo camphor hydrolase, CaMK, OCH, retro-Claisenase
EC Number 3.7.1.18
CAS Registry Number
Comments Isolated from?Rhodococcus?sp. The bornane ring system is cleaved by a retro-Claisen reaction to give the enol of ¦Á-campholonate. When separate from the enzyme the enol is tautomerised to the keto form as a 6:1 mixture of [(1S,3R)-2,2,3-trimethyl-4-oxocyclopentyl]acetate and [(1S,3S)-2,2,3-trimethyl-4-oxocyclopentyl]acetate.
Cofactor
History
Reactions Bornane-2,6-dione + H(2)O = ((1S)-4-hydroxy-2,2,3-trimethylcyclopent-3- enyl)acetate.

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