9,12-octadecadienoate 8-hydroperoxide 8S-isomerase EC#: 5.4.4.6; ChemWhat Code: 1383364

Product Name 9,12-octadecadienoate 8-hydroperoxide 8S-isomerase
Example Structure Example Structure of 9,12-octadecadienoate 8-hydroperoxide 8S-isomerase EC#: 5.4.4.6
Synonyms 7,8-diol synthase, 7,8-LDS, 7,8-linoleate diol synthase
EC Number 5.4.4.6
CAS Registry Number
Comments The enzyme contains heme. The bifunctional enzyme from?Gaeumannomyces graminis?catalyses the oxidation of linoleic acid to (8R,9Z,12Z)-8-hydroperoxyoctadeca-9,12-dienoate (cf. EC?1.13.11.60, linoleate 8R-lipoxygenase), which is then isomerized to (7S,8S,9Z,12Z)-5,8-dihydroxyoctadeca-9,12-dienoate [3].
Cofactor heme
History
Reactions (8R,9Z,12Z)-8-hydroperoxyoctadeca-9,12-dienoate = (7S,8S,9Z,12Z)-7,8- dihydroxyoctadeca-9,12-dienoate.

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