acetylacetone-cleaving enzyme EC#: 1.13.11.50; ChemWhat Code: 1374972

Product Name acetylacetone-cleaving enzyme
Example Structure Example Structure of acetylacetone-cleaving enzyme EC#: 1.13.11.50
Synonyms acetylacetone dioxygenase, acetylacetone-cleaving enzyme, b-diketone dioxygenase, cupin-type dioxygenase, diketone cleaving dioxygenase, diketone cleaving enzyme, diketone dioxygenase, diketone-cleaving dioxygenase, diketone-cleaving enzyme, Dke1, oxygenase, b-diketone di-, pentane-2,4-dione hydrolase
EC Number 1.13.11.50
CAS Registry Number 524047-53-8
Comments An Fe(II)-dependent enzyme. Forms the first step in the acetylacetone degradation pathway of Acinetobacter johnsonii. While acetylacetone is by far the best substrate, heptane-3,5-dione, octane-2,4-dione, 2-acetylcyclohexanone and ethyl acetoacetate can also act as substrates.
Cofactor Fe cation
History
Reactions Pentane-2,4-dione + O(2) = acetate + 2-oxopropanal.

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