acetylajmaline esterase EC#: 3.1.1.80; ChemWhat Code: 1379293
| Product Name | acetylajmaline esterase |
| Example Structure |  |
| Synonyms | |
| EC Number | 3.1.1.80 |
| CAS Registry Number | |
| Comments | This plant enzyme is responsible for the last stages in the biosynthesis of the indole alkaloid ajmaline. The enzyme is highly specific for the substrates 17-O-acetylajmaline and 17-O-acetylnorajmaline as the structurally related acetylated alkaloids vinorine, vomilenine, 1,2-dihydrovomilenine and 1,2-dihydroraucaffricine cannot act as substrates [2]. This is a novel member of the GDSL family of serine esterases/lipases. |
| Cofactor | |
| History | |
| Reactions | (1) 17-O-acetylajmaline + H(2)O = ajmaline + acetate. (2) 17-O-acetylnorajmaline + H(2)O = norajmaline + acetate. |
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