agroclavine dehydrogenase EC#: 1.5.1.46; ChemWhat Code: 1374422

Product Name agroclavine dehydrogenase
Example Structure Example Structure of agroclavine dehydrogenase EC#: 1.5.1.46
Synonyms agroclavine synthase, EasG
EC Number 1.5.1.46
CAS Registry Number
Comments The enzyme participates in the biosynthesis of ergotamine, an ergot alkaloid produced by some fungi of the Clavicipitaceae family. The reaction is catalysed in the opposite direction to that shown. The substrate for the enzyme is an iminium intermediate that is formed spontaneously from chanoclavine-I aldehyde in the presence of glutathione.
Cofactor
History
Reactions Agroclavine + NADP(+) = 6,8-dimethyl-6,7,8,9-tetradehydroergoline + Nadph.

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