(+)-alpha-pinene synthase EC#: 4.2.3.121; ChemWhat Code: 1382704

Product Name (+)-alpha-pinene synthase
Example Structure Example Structure of (+)-alpha-pinene synthase EC#: 4.2.3.121
Synonyms (+)-alpha-pinene cyclase, (+)-pinene cyclase, alpha pinene sythase, alpha-pinene sythase, AvPS, AvTPS1, cyclase I, cyclase III, limonene synthase, LIMS, More, pinene synthase, PINS, PlPIN, TPS-(+)apin1, TPS1
EC Number 4.2.3.121
CAS Registry Number
Comments Cyclase I of?Salvia officinalis?(sage) gives about equal parts (+)-¦Á-pinene and (+)-camphene, whereas cyclase III gives about equal parts of (+)-¦Á-pinene and (+)-¦Â-pinene. (3R)-Linalyl diphosphate can also be used by the enzyme in preference to (3S)-linalyl diphosphate. The 4-pro-R hydrogen of geranyl diphosphate is lost. Requires Mg2+?(preferred to Mn2+) [1-4]. With synthase II of?Pinus taeda?(loblolly pine) (+)-¦Â-pinene was the only product [5,6]. Requires Mn2+?(preferred to Mg2+). See also EC?4.2.3.122, (+)-¦Â-pinene synthase, and EC?4.2.3.116, (+)-camphene synthase.
Cofactor
History
Reactions Geranyl diphosphate = (+)-alpha-pinene + diphosphate.

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