Bis(3-allyl-4-hydroxyphenyl)sulfone CAS#: 41481-66-7; ChemWhat Code: 581350
Identification
Product Name | Bis(3-allyl-4-hydroxyphenyl)sulfone |
IUPAC Name | 4-(4-hydroxy-3-prop-2-enylphenyl)sulfonyl-2-prop-2-enylphenol |
Molecular Structure | |
CAS Registry Number | 41481-66-7 |
EINECS Number | No data available |
MDL Number | MFCD00691031 |
Beilstein Registry Number | No data available |
Synonyms | 3,3′-diallyl-4,4′-dihydroxydiphenyl sulfone4,4′-sulfonylbis[2-(2-propenyl)]phenol4,4′-sulfonylbis[2-(2-propenyl)phenol] |
Molecular Formula | C18H18O4S |
Molecular Weight | 330.398 |
InChI | InChI=1S/C18H18O4S/c1-3-5-13-11-15(7-9-17(13)19)23(21,22)16-8-10-18(20)14(12-16)6-4-2/h3-4,7-12,19-20H,1-2,5-6H2 |
InChI Key | MTMKZABGIQJAEX-UHFFFAOYSA-N |
Canonical SMILES | C=CCc1cc(ccc1O)S(=O)(=O)c2ccc(c(c2)CC=C)O |
Patent Information | ||
Patent ID | Title | Publication Date |
JP2017/125166 | COCRYSTAL COMPOUND COMPRISING FLUORAN COMPOUND AND 4,4′-SULFONYLDIPHENOL DERIVATIVE AND USE THEREFOR | 2017 |
Physical Data
Appearance | White powder |
Solubility | No data available |
Flash Point | No data available |
Refractive index | No data available |
Sensitivity | No data available |
Melting Point, °C |
152.6 |
154 – 155 |
154 – 156 |
143.05 – 145.05 |
151 – 152 |
Spectra
Description (NMR Spectroscopy) | Nucleus (NMR Spectroscopy) | Solvents (NMR Spectroscopy) | Frequency (NMR Spectroscopy), MHz | Original Text (NMR Spectroscopy) |
Chemical shifts | 1H | dimethylsulfoxide-d6 | ||
1H | dimethylsulfoxide-d6 | 300 | H NMR (300 MHz, DMSO-d 6 ) d 3.30 (d, 4, CH2) 5.20 (d, 4, vinyl), 5.91-6.00 (m, 2, vinyl), 6.85 (d, 1, aromatic), 7.57 (d, 2, aromatic) | |
Spin-spin coupling constants | 13C | dimethylsulfoxide-d6 |
Description (Mass Spectrometry) | Comment (Mass Spectrometry) |
electrospray ionisation (ESI) | |
electrospray ionisation (ESI), spectrum | |
Molecular peak |
Route of Synthesis (ROS)
Conditions | Yield |
With α-alanine-N-diacetic acid at 198 – 200℃; for 7h; Temperature; Inert atmosphere; | 96.2% |
With 1,10-Phenanthroline; ethylenediaminetetraacetic acid; sodium hydroxide In paraffin oil at 203 – 207℃; for 7h; Inert atmosphere; | 93.7% |
With iron(III) chloride In 1,2-dichloro-ethane at 60℃; for 15h; Reagent/catalyst; Solvent; Temperature; | 93.9% |
Safety and Hazards
Pictogram(s) | |
Signal | Warning |
GHS Hazard Statements | H317: May cause an allergic skin reaction [Warning Sensitization, Skin] H411: Toxic to aquatic life with long lasting effects [Hazardous to the aquatic environment, long-term hazard] Information may vary between notifications depending on impurities, additives, and other factors. |
Precautionary Statement Codes | P261, P272, P273, P280, P302+P352, P321, P333+P313, P362+P364, P391, and P501 (The corresponding statement to each P-code can be found at the GHS Classification page.) |
Other Data
Transportation | NONH for all modes of transport |
Under the room temperature and away from light | |
HS Code | No data available |
Storage | Under the room temperature and away from light |
Shelf Life | 2 years |
Market Price | USD |
Druglikeness | |
Lipinski rules component | |
Molecular Weight | 330.405 |
logP | 4.348 |
HBA | 2 |
HBD | 2 |
Matching Lipinski Rules | 4 |
Veber rules component | |
Polar Surface Area (PSA) | 82.98 |
Rotatable Bond (RotB) | 6 |
Matching Veber Rules | 2 |
Use Pattern |
Bis(3-allyl-4-hydroxyphenyl)sulfone CAS#: 41481-66-7 Used as the Thermal developer. |
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Approved Manufacturers | |
Warshel Chemical Ltd | http://www.warshel.com/ |
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