Bis(4-methylphenyl)iodonium hexafluorophosphate CAS#: 60565-88-0; ChemWhat Code: 927277
Identification
| Product Name | Bis(4-methylphenyl)iodonium hexafluorophosphate |
| IUPAC Name | bis(4-methylphenyl)iodanium;hexafluorophosphate |
| Molecular Structure |  |
| CAS Registry Number | 60565-88-0 |
| EINECS Number | 262-301-5 |
| MDL Number | MFCD06656584 |
| Beilstein Registry Number | 3581445 |
| Synonyms | bis(4-methylphenyl)iodonium hexafluorophosphate, 4,4′-dimethyldiphenyl iodonium phosphorushexafluoride, bis(4-methylphenyl)iodonium hexafluorophosphate, iodonium bis(4-methylphenyl)hexafluorophosphate, Di-p-tolyliodonium hexafluorophosphate, bis(p-tolyl)iodine hexafluorophosphate, bis(p-tolyl)iodonium hexafluorophosphate |
| Molecular Formula | C14H14I*F6P |
| Molecular Weight | 454.134 |
| InChI | InChI=1S/C14H14I.F6P/c1-11-3-7-13(8-4-11)15-14-9-5-12(2)6-10-14;1-7(2,3,4,5)6/h3-10H,1-2H3;/q+1;-1 |
| InChI Key | LHLVGWWCRPPKBC-UHFFFAOYSA-N |
| Canonical SMILES | CC1=CC=C(C=C1)[I+]C2=CC=C(C=C2)C.F[P-](F)(F)(F)(F)F |
| Patent Information | ||
| Patent ID | Title | Publication Date |
| CN106866527 | A quinoline – 2 – synthetic method of imine derivative (by machine translation) | 2017 |
| CN104151255 | A multi-substituted quinazoline imine derivatives and its preparation method (by machine translation) | 2016 |
| WO2005/34884 | DENTAL COMPOSITIONS AND METHODS WITH ARYLSULFINATE SALTS | 2005 |
| US6458865 | Photopolymerizable vinyl ether based monomeric formulations and polymerizable compositions which may include certain novel spiroorthocarbonates | 2002 |
Physical Data
| Appearance | White powder |
| Melting Point, °C | 175.5 – 177.2 |
Spectra
| Description (NMR Spectroscopy) | Nucleus (NMR Spectroscopy) |
| Chemical shifts | 1H |
| Description (IR Spectroscopy) |
| ATR (attenuated total reflectance), Bands, Spectrum |
| Bands, Spectrum |
| Description (Mass Spectrometry) | Comment (Mass Spectrometry) |
| spectrum | FAB (fast atom bombardment) |
| Description (UV/VIS Spectroscopy) | Solvent (UV/VIS Spectroscopy) | Absorption Maxima (UV/VIS), nm | Ext./Abs. Coefficient, l·mol-1cm-1 |
| Spectrum | dichloromethane | ||
| Spectrum | 246.3 | 17946.5 |
| Description (Luminescence Spectroscopy) | Comment (Luminescence Spectroscopy) |
| Luminescence quenching | Quenching with N,N-dimethylaniline |
Route of Synthesis (ROS)
| Conditions | Yield |
| With potassium hexafluorophosphate In acetonitrile for 24h Inert atmosphere Sealed tube |
Safety and Hazards
| Pictogram(s) |  |
| Signal | Danger |
| GHS Hazard Statements | H314: Causes severe skin burns and eye damage [Danger Skin corrosion/irritation] Information may vary between notifications depending on impurities, additives, and other factors. |
| Precautionary Statement Codes | P260, P264, P280, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P321, P363, P405, and P501 (The corresponding statement to each P-code can be found at the GHS Classification page.) |
Other Data
| Transportation | Class 8; Packaging Group: II; UN Number: 1759 |
| Under the room temperature and away from light | |
| HS Code | 294200 |
| Storage | Under the room temperature and away from light |
| Market Price | USD 120/kg |
| Use Pattern |
| Bis(4-methylphenyl)iodonium hexafluorophosphate CAS 60565-88-0 is usually used as a Photoinitiator |
| Bis(4-methylphenyl)iodonium hexafluorophosphate is a white powder. It melts at 175-180 °C and shows an UV absorption peak at 267nm. 1 |
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Approved Manufacturers | |
| Warshel Chemical Ltd | https://www.warshel.com/ |
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Other Suppliers | |
| Watson International Limited | Visit Watson Official Website |
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