Butyldi-1-adamantylphosphine CAS#: 321921-71-5; ChemWhat Code: 38672
Identification
Product Name | Butyldi-1-adamantylphosphine |
IUPAC Name | bis(1-adamantyl)-butylphosphane |
Molecular Structure | |
CAS Registry Number | 321921-71-5 |
EINECS Number | No data availabe |
MDL Number | MFCD05861606 |
Beilstein Registry Number | 8726448 |
Synonyms | catacxium A, di-(1-adamantyl)-n-butylphosphine, rac-((3R,5R,7R)-adamantan-1-yl)((3S,5S,7S)-adamantan-1-yl)(butyl)phosphane, butyl(ditricyclo[3.3.1.1∼3,7∼]dec-1-yl)phosphane, butylbis(tricyclo[3.3.1.13,7]dec-1-yl)phosphine, butylditricyclo[3.3.1.1(3,7)]decan-1-ylphosphane, di((3S,5S,7S)-adamantan-1-yl)(butyl)phosphine |
Molecular Formula | C24H39P |
Molecular Weight | 358.54 |
InChI | InChI=1S/C24H39P/c1-2-3-4-25(23-11-17-5-18(12-23)7-19(6-17)13-23)24-14-20-8-21(15-24)10-22(9-20)16-24/h17-22H,2-16H2,1H3/t17-,18+,19-,20-,21+,22-,23-,24- |
InChI Key | HTJWUNNIRKDDIV-FECFBMJZSA-N |
Canonical SMILES | CCCCP([C@@]12C[C@H]3C[C@@H](C1)C[C@@H](C2)C3)[C@@]45C[C@H]6C[C@@H](C4)C[C@@H](C5)C6 |
Patent Information | ||
Patent ID | Title | Publication Date |
US2013/26426 | CARBAZOLE DERIVATIVE AND SEMICONDUCTOR NANOCRYSTAL | 2013 |
US2015/80628 | CATALYST AND PROCESS FOR THE CO-DIMERIZATION OF ETHYLENE AND PROPYLENE | 2015 |
EP1473297 | PROCESS FOR PRODUCING TERTIARY PHOSPHINE HAVING BULKY HYDROCARBON GROUP BONDED | 2004 |
Physical Data
Appearance | White to yellow solid |
Sensitivity | air sensitive |
Melting Point, °C | Solvent (Melting Point) |
108 – 110 | ethanol |
102 |
Spectra
Description (NMR Spectroscopy) | Nucleus (NMR Spectroscopy) | Coupling Nuclei | Solvents (NMR Spectroscopy) | Frequency (NMR Spectroscopy), MHz |
Chemical shifts | 1H | benzene-d6 | 250 | |
Chemical shifts | 1H | 1H | benzene-d6 | 250 |
Chemical shifts | 13C | benzene-d6 | 62 | |
Chemical shifts | 13C | 31P | benzene-d6 | 62 |
Chemical shifts | 31P | benzene-d6 |
Description (IR Spectroscopy) | Solvent (IR Spectroscopy) |
Bands | KBr |
Description (Mass Spectrometry) |
spectrum, electron impact (EI) |
Route of Synthesis (ROS)
Conditions | Yield |
With selenium In chloroform-d1 at 60℃; for 0.666667h; Inert atmosphere; | 100% |
Safety and Hazards
Pictogram(s) | |
Signal | Warning |
GHS Hazard Statements | H302 (50%): Harmful if swallowed [Warning Acute toxicity, oral] H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation] H319 (100%): Causes serious eye irritation [Warning Serious eye damage/eye irritation] H332 (50%): Harmful if inhaled [Warning Acute toxicity, inhalation] H335 (100%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation] Information may vary between notifications depending on impurities, additives, and other factors. |
Precautionary Statement Codes | P261, P264, P270, P271, P280, P301+P312, P302+P352, P304+P312, P304+P340, P305+P351+P338, P312, P321, P330, P332+P313, P337+P313, P362, P403+P233, P405, and P501 (The corresponding statement to each P-code can be found at the GHS Classification page.) |
Other Data
Transportation | NONH for all modes of transport |
Under the room temperature and away from light | |
HS Code | 293100 |
Storage | Under the room temperature and away from light |
Shelf Life | 2 years |
Market Price | USD |
Use Pattern |
Used as a catalyst. |
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Approved Manufacturers | |
Warshel Chemical Ltd | http://www.warshel.com/ |
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