chrysanthemyl diphosphate synthase EC#: 2.5.1.67; ChemWhat Code: 1377983

Product Name chrysanthemyl diphosphate synthase
Example Structure Example Structure of chrysanthemyl diphosphate synthase EC#: 2.5.1.67
Synonyms CDS, CDS_CCI2, chrysanthemol synthase, chrysanthemyl diphosphate synthase, CPP, CPP synthase, CPPase, FDS-5
EC Number 2.5.1.67
CAS Registry Number
Comments Requires a divalent metal ion for activity, with Mg2+ being better than Mn2+ [1]. Chrysanthemyl diphosphate is a monoterpene with a non-head-to-tail linkage. It is unlike most monoterpenoids, which are derived from geranyl diphosphate and have isoprene units that are linked head-to-tail. The mechanism of its formation is similar to that of the early steps of squalene and phytoene biosynthesis. Chrysanthemyl diphosphate is the precursor of chrysanthemic acid, the acid half of the pyrethroid insecticides found in chrysanthemums.
Cofactor Mn2+ or Mg2+
History
Reactions 2 dimethylallyl diphosphate = diphosphate + chrysanthemyl diphosphate.

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