crotonyl-CoA carboxylase/reductase EC#: 1.3.1.85; ChemWhat Code: 1374051

Product Name crotonyl-CoA carboxylase/reductase
Example Structure Example Structure of crotonyl-CoA carboxylase/reductase EC#: 1.3.1.85
Synonyms 2-octenoyl-CoA carboxylase/reductase, AntE, CCR, CCR1, CCRC, crotonyl-CoA carboxylase/reductase, crotonyl-CoA reductase (carboxylating), crotonyl-CoA reductase-carboxylase, pteB, rimJ
EC Number 1.3.1.85
CAS Registry Number
Comments The reaction is catalysed in the reverse direction. This enzyme, isolated from the bacterium Rhodobacter sphaeroides, catalyses (E)-but-2-enoyl-CoA-dependent oxidation of NADPH in the presence of CO2. When CO2 is absent, the enzyme catalyses the reduction of (E)-but-2-enoyl-CoA to butanoyl-CoA, but with only 10% of maximal activity (relative to (E)-but-2-enoyl-CoA carboxylation).
Cofactor
History
Reactions (2S)-ethylmalonyl-CoA + NADP(+) = (E)-but-2-enoyl-CoA + CO(2) + Nadph.

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