demethyl-4-deoxygadusol synthase EC#: 4.2.3.154; ChemWhat Code: 1382751

Product Name demethyl-4-deoxygadusol synthase
Example Structure Example Structure of demethyl-4-deoxygadusol synthase EC#: 4.2.3.154
Synonyms Ava_3858, DDGS, desmethyl-4-deoxygadusol synthase, Npun_5600
EC Number 4.2.3.154
CAS Registry Number
Comments The enzyme, characterized from the cyanobacterium?Nostoc punctiforme?PCC 73102, is involved in the biosynthesis of the sunscreen compound shinorine. It requires a divalent metal ion (Zn2+?or Co2+) and an NAD+?cofactor, which is transiently reduced during the reaction.?cf. EC?4.2.3.152, 2-epi-5-epi-valiolone synthase and EC?4.2.3.155, 2-epi-valiolone synthase.
Cofactor NAD+ Co2+ or Zn2+
History
Reactions D-sedoheptulose 7-phosphate = demethyl-4-deoxygadusol + phosphate + H(2)O.

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