(E)-2-methylbutanal oxime monooxygenase EC#: 1.14.14.41; ChemWhat Code: 1375549

Product Name (E)-2-methylbutanal oxime monooxygenase
Example Structure Example Structure of (E)-2-methylbutanal oxime monooxygenase EC#: 1.14.14.41
Synonyms CYP71E7
EC Number 1.14.14.41
CAS Registry Number
Comments This cytochrome P-450 (heme thiolate) enzyme is involved in the biosynthesis of the cyanogenic glucosides lotaustralin and linamarin. It catalyses three different activities – isomerization of its substrate the (E) isomer to the (Z) isomer, dehydration, and C-hydroxylation.
Cofactor
History
Reactions (1) (E)-2-methylbutanal oxime + [reduced NADPH–hemoprotein reductase] + O(2) = 2-hydroxy-2-methylbutanenitrile + [oxidized NADPH–hemoprotein reductase] + 2 H(2)O. (2) (E)-2-methylpropanal oxime + [reduced NADPH–hemoprotein reductase] + O(2) = 2-hydroxy-2-methylpropanenitrile + [oxidized NADPH–hemoprotein reductase] + 2 H(2)O.

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