homomethionine N-monooxygenase EC#: 1.14.14.42; ChemWhat Code: 1375550
| Product Name | homomethionine N-monooxygenase |
| Example Structure |  |
| Synonyms | CYP79F1, CYP79F2, dihomomethionine N-hydroxylase, hexahomomethionine N-hydroxylase |
| EC Number | 1.14.14.42 |
| CAS Registry Number | |
| Comments | This plant cytochrome P-450 (heme thiolate) enzyme is involved in methionine-derived aliphatic glucosinolates biosynthesis. It catalyses two successive N-hydroxylations, which are followed by dehydration and decarboxylation. CYP79F1 from Arabidopsis thaliana can metabolize homo-, di-, tri-, tetra-, penta-, and hexahomomethionine to their corresponding aldoximes, while CYP79F2 from the same plant can only metabolize penta- and hexahomomethionine. |
| Cofactor | heme-thiolate |
| History | |
| Reactions | An L-polyhomomethionine + 2 O(2) + 2 [reduced NADPH–hemoprotein reductase] = an omega-(methylthio)-(E)-alkanal oxime + CO(2) + 3 H(2)O + 2 [oxidized NADPH–hemoprotein reductase]. |
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