L-evernosamine nitrososynthase EC#: 1.14.13.187; ChemWhat Code: 1375424

Product Name L-evernosamine nitrososynthase
Example Structure Example Structure of L-evernosamine nitrososynthase EC#: 1.14.13.187
Synonyms DnmZ, nitrososynthase, ORF36
EC Number 1.14.13.187
CAS Registry Number
Comments Requires FAD. Isolated from the bacterium Micromonospora carbonacea var. africana. The nitroso group is probably spontaneously oxidized to a nitro group giving dTDP-¦Â-L-evernitrose, which is involved in the biosynthesis of the antibiotic everninomycin. The reaction was studied using dTDP-¦Â-L-4-epi-vancosamine (dTDP-4-O-desmethyl-¦Â-L-evernitrosamine).
Cofactor FAD
History
Reactions dTDP-beta-L-evernosamine + 2 Nadph + 2 O(2) = dTDP-2,3,6-trideoxy-3- C-methyl-4-O-methyl-3-nitroso-beta-L-arabino-hexopyranose + 2 NADP(+) + 3 H(2)O.

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