oligosaccharide 4-alpha-D-glucosyltransferase EC#: 2.4.1.161; ChemWhat Code: 1377453

Product Name oligosaccharide 4-alpha-D-glucosyltransferase
Example Structure Example Structure of oligosaccharide 4-alpha-D-glucosyltransferase EC#: 2.4.1.161
Synonyms 1,4-alpha-glucan:1,4-alpha-glucan 4-alpha-glucosyltransferase, amylase III
EC Number 2.4.1.161
CAS Registry Number 9000-92-4
Comments The enzyme acts on amylose, amylopectin, glycogen and maltooligosaccharides. No detectable free glucose is formed, indicating the enzyme does not act as a hydrolase. The enzyme from the bacterium Cellvibrio japonicus has the highest activity with maltotriose as a donor, and also accepts maltose [3], while the enzyme from amoeba does not accept maltose [1,2]. Oligosaccharides with 1¡ú6 linkages cannot function as donors, but can act as acceptors [3]. Unlike EC 2.4.1.25, 4-¦Á-glucanotransferase, this enzyme can transfer only a single glucosyl residue.
Cofactor
History
Reactions Transfers the non-reducing terminal alpha-D-glucose residue from a (1->4)-alpha-D-glucan to the 4-position of a free glucose or of a glucosyl residue at the non-reducing terminus of a (1->4)-alpha-D-glucan, thus bringing about the rearrangement of oligosaccharides.

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