phenylacetaldehyde oxime monooxygenase EC#: 1.14.14.44; ChemWhat Code: 1375552

Product Name phenylacetaldehyde oxime monooxygenase
Example Structure Example Structure of phenylacetaldehyde oxime monooxygenase EC#: 1.14.14.44
Synonyms CYP71AN24
EC Number 1.14.14.44
CAS Registry Number
Comments This cytochrome P450 (heme-thiolate) enzyme is involved in the biosynthesis of the cyanogenic glucosides (R)-prunasin and (R)-amygdalin. It catalyses three different activities – isomerization of the (E) isomer to the (Z) isomer, dehydration, and C-hydroxylation.
Cofactor heme-thiolate
History
Reactions (E)-phenylacetaldehyde oxime + [reduced NADPH–hemoprotein reductase] + O(2) = (R)-mandelonitrile + [oxidized NADPH–hemoprotein reductase] + 2 H(2)O.

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