phenylacetone monooxygenase EC#: 1.14.13.92; ChemWhat Code: 1375317

Product Name phenylacetone monooxygenase
Example Structure Example Structure of phenylacetone monooxygenase EC#: 1.14.13.92
Synonyms 4-hydroxyacetophenone monooxygenase, Baeyer-Villiger monooxygenase, BVMO, EtaA, HAPMO, M-PAMO, More, PAMO, phenylacetone monooxygenase
EC Number 1.14.13.92
CAS Registry Number
Comments A flavoprotein (FAD). NADH cannot replace NADPH as coenzyme. In addition to phenylacetone, which is the best substrate found to date, this Baeyer-Villiger monooxygenase can oxidize other aromatic ketones [1-(4-hydroxyphenyl)propan-2-one, 1-(4-hydroxyphenyl)propan-2-one and 3-phenylbutan-2-one], some alipatic ketones (e.g. dodecan-2-one) and sulfides (e.g. 1-methyl-4-(methylsulfanyl)benzene).
Cofactor FAD
History
Reactions Phenylacetone + Nadph + O(2) = benzyl acetate + NADP(+) + H(2)O.

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