phenylglyoxylate dehydrogenase (acylating) EC#: 1.2.1.58; ChemWhat Code: 1373811

Product Name phenylglyoxylate dehydrogenase (acylating)
Example Structure Example Structure of phenylglyoxylate dehydrogenase (acylating) EC#: 1.2.1.58
Synonyms Dehydrogenase, phenylglyoxylate (CoA-benzoylating), Phenylglyoxal:NAD+ oxidoreductase (CoA benzoylating), Phenylglyoxylate dehydrogenase (CoA benzoylating), Phenylglyoxylate-acceptor oxidoreductase, Phenylglyoxylate:acceptor oxidoreductase
EC Number 1.2.1.58
CAS Registry Number 205510-78-7
Comments Requires thiamine diphosphate as cofactor. The enzyme from the denitrifying bacterium Azoarcus evansii is specific for phenylglyoxylate. 2-Oxoisovalerate is oxidized at 15% of the rate for phenylglyoxylate. Also reduces viologen dyes. Contains iron-sulfur centres and FAD.
Cofactor iron-sulfur;FAD;thiamine diphosphate
History
Reactions Phenylglyoxylate + NAD(+) + CoA = benzoyl-S-CoA + CO(2) + Nadh.

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