phloroisovalerophenone synthase EC#: 2.3.1.156; ChemWhat Code: 1376949

Product Name phloroisovalerophenone synthase
Example Structure Example Structure of phloroisovalerophenone synthase EC#: 2.3.1.156
Synonyms 3-methyl-1-(trihydroxyphenyl)butan-1-one synthase, bifunctional chalcone/(iso)valerophenone synthase, CHS2-1, phlorisovalerophenone synthase, valerophenone synthase, VPS
EC Number 2.3.1.156
CAS Registry Number
Comments Closely related to EC 2.3.1.74, naringenin-chalcone synthase. The product, 3-methyl-1-(2,4,6-trihydroxyphenyl)butan-1-one, is phloroisovalerophenone. Also acts on isobutyryl-CoA as substrate to give phlorisobutyrophenone. The products are intermediates in the biosynthesis of the bitter (¦Á) acids in hops (Humulus lupulus).
Cofactor
History
Reactions Isovaleryl-CoA + 3 malonyl-CoA = 4 CoA + 3 CO(2) + 3-methyl-1-(2,4,6- trihydroxyphenyl)butan-1-one.

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