phosphinomethylmalate isomerase EC#: 4.2.1.166; ChemWhat Code: 1382484

Product Name phosphinomethylmalate isomerase
Example Structure Example Structure of phosphinomethylmalate isomerase EC#: 4.2.1.166
Synonyms PMI
EC Number 4.2.1.166
CAS Registry Number
Comments The enzyme, characterized from the bacterium?Streptomyces viridochromogenes, is involved in bialaphos biosynthesis. The enzyme from the bacterium?Kitasatospora phosalacinea?participates in the biosynthesis of the related compound phosalacine. Both compounds contain the nonproteinogenic amino acid?L-phosphinothricin that acts as a potent inhibitor of EC?6.3.1.2, glutamine synthetase. The similar enzyme EC?4.2.1.3, aconitate hydratase, cannot catalyse this reaction.
Cofactor
History
Reactions Phosphinomethylmalate = phosphinomethylisomalate.

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