(R)-dichlorprop dioxygenase (2-oxoglutarate) EC#: 1.14.11.44; ChemWhat Code: 1375136

Product Name (R)-dichlorprop dioxygenase (2-oxoglutarate)
Example Structure Example Structure of (R)-dichlorprop dioxygenase (2-oxoglutarate) EC#: 1.14.11.44
Synonyms (R)-phenoxypropionate/alpha-ketoglutarate-dioxygenase, 2-oxoglutarate-dependent (R)-dichlorprop dioxygenase, AAD-1, alpha-ketoglutarate-dependent (R)-dichlorprop dioxygenase, ariloxyalkanoate-dioxygenase-1, RdpA
EC Number 1.14.11.44
CAS Registry Number
Comments Fe2+-dependent enzyme. The enzymes from the Gram-negative bacteria Delftia acidovorans MC1 and Sphingomonas herbicidovorans MH are involved in the degradation of the (R)-enantiomer of the phenoxyalkanoic acid herbicides mecoprop and dichlorprop [1,2].
Cofactor Fe2+
History
Reactions (1) (R)-2-(4-chloro-2-methylphenoxy)propanoate + 2-oxoglutarate + O(2) = 4-chloro-2-methylphenol + pyruvate + succinate + CO(2). (2) (R)-(2,4-dichlorophenoxy)propanoate + 2-oxoglutarate + O(2) = 2,4- dichlorophenol + pyruvate + succinate + CO(2).

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