Rhizobium leguminosarum exopolysaccharide glucosyl ketal-pyruvate-transferase EC#: 2.5.1.98; ChemWhat Code: 1378034

Product Name Rhizobium leguminosarum exopolysaccharide glucosyl ketal-pyruvate-transferase
Example Structure Example Structure of Rhizobium leguminosarum exopolysaccharide glucosyl ketal-pyruvate-transferase EC#: 2.5.1.98
Synonyms
EC Number 2.5.1.98
CAS Registry Number
Comments The enzyme is responsible for pyruvylation of subterminal glucose in the acidic octasaccharide repeating unit of the exopolysaccharide of Rhizobium leguminosarum (bv. viciae strain VF39) which is necessary to establish nitrogen-fixing symbiosis with Pisum sativum, Vicia faba, and Vicia sativa.
Cofactor
History
Reactions Phosphoenolpyruvate + [D-GlcA-beta-(1->4)-2-O-Ac-D-GlcA-beta-(1->4)-D- Glc-beta-(1->4)-(3-O-CH(3)-CH(2)CH(OH)C(O)-D-Gal-beta-(1->4)-D-Glc-beta- (1->4)-D-Glc-beta-(1->4)-D-Glc-beta-(1->6))-2(or3)-O-Ac-D-Glc-alpha- (1->6)](n) = [D-GlcA-beta-(1->4)-2-O-Ac-D-GlcA-beta-(1->4)-D-Glc-beta- (1->4)-(3-O-CH(3)-CH(2)CH(OH)C(O)-D-Gal-beta-(1->3)-4,6-CH(3)(COO(-))C-D- Glc-beta-(1->4)-D-Glc-beta-(1->4)-D-Glc-beta-(1->6))-2(or3)-O-Ac-D-Glc- alpha-(1->6)](n) + phosphate.

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