tenuazonic acid synthetase EC#: 6.3.2.50; ChemWhat Code: 1383793
| Product Name | tenuazonic acid synthetase |
| Example Structure |  |
| Synonyms | TAS1, TeA synthetase 1 |
| EC Number | 6.3.2.50 |
| CAS Registry Number | |
| Comments | This fungal enzyme, isolated from?Magnaporthe oryzae, is an non-ribosomal peptide synthetase (NRPS)-polyketide synthase (PKS) hybrid protein that consists of condensation (C), adenylation (A) and peptidyl-carrier protein (PCP) domains in the NRPS portion and a ketosynthase (KS) domain in the PKS portion. ATP is required for activation of isoleucine, which is then condensed with acetoacetyl-CoA. Cyclization and release from the enzyme are catalysed by the KS domain. |
| Cofactor | |
| History | |
| Reactions | Atp + L-isoleucine + acetoacetyl-CoA = amp + diphosphate + tenuazonic acid + CoA. |
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