toluene methyl-monooxygenase EC#: 1.14.15.26; ChemWhat Code: 1375717
| Product Name | toluene methyl-monooxygenase |
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| Synonyms | ntnM, xylM |
| EC Number | 1.14.15.26 |
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| Comments | The enzyme, characterized from several Pseudomonas strains, catalyses the first step in the degradation of toluenes and xylenes. It has a broad substrate specificity and is also active with substituted compounds, such as chlorotoluenes. The electrons are provided by a reductase (EC 1.18.1.3, ferredoxin¡ªNAD+ reductase) that transfers electrons from NADH via FAD and an [2Fe-2S] cluster. The enzyme can also act on its products, producing gem-diols that spontaneously dehydrate to form aldehydes. |
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