triethylindium CAS#: 923-34-2; ChemWhat Code: 1290789

IdentificationPhysical DataSpectra
Route of Synthesis (ROS)Safety and HazardsOther Data

Identification

Product Nametriethylindium
IUPAC Nametriethylindigane
Molecular Structuretriethylindium-CAS-923-34-2
CAS Registry Number 923-34-2
EINECS Number213-095-0
Synonyms3-Pyridinamin;3-Pyridinamine;3-Pyridinamine;pyridin-3-amine;T6NJ CZ;3- Aminopyridine;3-Amino-pyridine;3-pyridylamine;Amino-3 pyridine;m-Aminopyridine;MS/MS-1064463;Pyridin-3-ylamine;Pyridine, 3-amino-;β-Aminopyridine
462-08-8
Molecular FormulaC6H15In
Molecular Weight202g/mol 
InChIInChI=1S/3C2H5.In/c3*1-2;/h3*1H2,2H3
InChI KeyOTRPZROOJRIMKW-UHFFFAOYSA-N
Isomeric SMILESCC[In](CC)CC
Patent Information
Patent IDTitlePublication Date
WO2014/78263METHODS OF PRODUCING TRIMETHYLGALLIUM2014
US2004/122248Preparation of organometal compounds2004
US2003/191333Trialkylindium preparation2003

Physical Data

No data available

Melting Point, °C
-32
Density, g·cm-3Reference Temperature, °CMeasurement Temperature, °C
1.26420
Description (Association (MCS))Solvent (Association (MCS))
AdsorptionCCl4
Adsorptionindium antimonide
AdsorptionGaAs(100)

Spectra

Description (NMR Spectroscopy)Nucleus (NMR Spectroscopy)Solvents (NMR Spectroscopy)Temperature (NMR Spectroscopy), °C
Chemical shifts, Spectrum1Hbenzene-d625
Chemical shifts, Spectrum1H(2)H8-toluene25
Description (UV/VIS Spectroscopy)Comment (UV/VIS Spectroscopy)
Spectrum190 nm – 390 nm
Absorption maximaRatio of solvents: 0.1N

Route of Synthesis (ROS)

Route of Synthesis (ROS) of triethylindium CAS 923-34-2

Route of Synthesis (ROS) of triethylindium CAS 923-34-2

ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); tris(2-thienyl)phosphine In tetrahydrofuran at 60℃; for 4h; Inert atmosphere;

Experimental Procedure
General procedure: 4-Tosyloxyquinazoline derivatives 2 were obtained by using our reported method.5e A solution of quinazolin-4-ones 1 (0.2 mmol) in THF (2 mL) was treated with TsCl (1.2 equiv) and K2CO3 (3.0 equiv) at 60 °C. Upon completion of the reaction as indicated by TLC, the solvent was evaporated and the residue was purified on silica gel to give product 2. To a mixture of 4-tosyloxyquinazoline 2 (0.20 mmol) and organoindium reagent9 3 (1.0 equiv) in anhydrous THF (2.0 mL), Pd2(dba)3 (1 mol%) and (2-furyl)3P (2 mol%) were added. The mixture was stirred and heated at 60 °C under N2. Upon completion of the reaction as indicated by TLC, the solvent was evaporated. The residue was then diluted with EtOAc (10 mL), washed with H2O (10 mL), and dried with anhydrous MgSO4. Evaporation of the solvent followed by purification on silica gel (PE-EtOAc, 50:1 to 20:1) provided the corresponding product 4.
73%

Safety and Hazards

Pictogram(s)
SignalDanger
GHS Hazard StatementsH250 (100%): Catches fire spontaneously if exposed to air [Danger Pyrophoric liquids]
H314 (97.44%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]
Precautionary Statement CodesP210, P222, P231, P233, P260, P264, P280, P301+P330+P331, P302+P335+P334, P302+P361+P354, P304+P340, P305+P354+P338, P316, P321, P363, P370+P378, P405, and P501
(The corresponding statement to each P-code can be found at the GHS Classification page.)

Other Data

Shelf Life1 year
Druglikeness
Lipinski rules component
Molecular Weight202.005
logP2.658
HBA0
HBD0
Matching Lipinski Rules4
Veber rules component
Polar Surface Area (PSA)0
Rotatable Bond (RotB)3
Matching Veber Rules2
Use Pattern
triethylindium CAS#: 923-34-2 is a key precursor in thin film deposition technologies like CVD and ALD. It is used to deposit high-quality indium compound films in the semiconductor industry and other fields.
Triethylindium can be employed in the preparation of indium compound films for use in optoelectronic devices, including solar cells and light-emitting diodes (LEDs). And Triethylindium is a crucial precursor in the semiconductor industry, used for depositing indium compound films, such as indium gallium alloys (InGaAs). These films have important applications in electronic devices and optoelectronics, such as high-electron-mobility transistors (HEMTs) and laser devices.
Triethylindium is also utilized in metalorganic chemistry as an organometallic precursor, participating in some organic synthesis reactions.

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