TRIS(4-ETHOXYPHENYL)BISMUTH CAS#: 90591-48-3; ChemWhat Code: 1296140
Identification
| Product Name | TRIS(4-ETHOXYPHENYL)BISMUTH |
| IUPAC Name | tris(4-ethoxyphenyl)bismuthane |
| Molecular Structure |  |
| CAS Registry Number | 90591-48-3 |
| Synonyms | TEPB, tris-(4-ethoxy-phenyl)-bismuthine, tri(p-ethoxyphenyl)bismuth, Tris-(4-aethoxy-phenyl)-bismutin, Tris-(4-aethoxy-phenyl)-wismut |
| Molecular Formula | C24H27BiO3 |
| Molecular Weight | 572.457 |
| InChI | InChI=1S/3C8H9O.Bi/c3*1-2-9-8-6-4-3-5-7-8;/h3*4-7H,2H2,1H3; |
| InChI Key | PBBDAZHUSYNCOV-UHFFFAOYSA-N |
| Canonical SMILES | CCOC1=CC=C(C=C1)[Bi](C2=CC=C(C=C2)OCC)C3=CC=C(C=C3)OCC |
| Patent Information | ||
| Patent ID | Title | Publication Date |
| US2015/112104 | Process For Producing Chlorinated Hydrocarbons In The Presence Of A Polyvalent Bismuth Compound | 2015 |
| EP2133357 | LIVING RADICAL POLYMERIZATION PROMOTER | 2009 |
| US2006/148842 | Nepetalactams and N-substituted derivatives thereof | 2006 |
| US4225517 | Process for the production of acetaldehyde by the reaction of methanol with synthesis gas | 1980 |
| US4364872 | Method of making aluminum alkyls | 1982 |
Physical Data
| Appearance | White or off-white crystal |
| Melting Point, °C | Solvent (Melting Point) |
| 73 | |
| 87 – 88 | methanol |
| 86 – 87 |
Spectra
| Nucleus (NMR Spectroscopy) | Solvents (NMR Spectroscopy) |
| 1H | dimethylsulfoxide-d6 |
| TRIS(4-ETHOXYPHENYL)BISMUTH CAS#: 90591-48-3 HNMR |  |
| TRIS(4-ETHOXYPHENYL)BISMUTH CAS#: 90591-48-3 HPLC |  |
Route of Synthesis (ROS)
| Conditions | Yield |
| Stage #1: bromobenzene With magnesium In tetrahydrofuran Inert atmosphere; Reflux; Stage #2: bismuth(III) chloride In tetrahydrofuran at -10 – 65℃; for 1.5h; Inert atmosphere; | 51.8% |
Safety and Hazards
| Pictogram(s) |  |
| Signal | Danger |
| GHS Hazard Statements | H302: Harmful if swallowed [Warning Acute toxicity, oral] H312: Harmful in contact with skin [Warning Acute toxicity, dermal] H332: Harmful if inhaled [Warning Acute toxicity, inhalation] Information may vary between notifications depending on impurities, additives, and other factors. |
| Precautionary Statement Codes | P261, P264, P270, P271, P280, P301+P312, P302+P352, P304+P312, P304+P340, P312, P322, P330, P363, and P501 (The corresponding statement to each P-code can be found at the GHS Classification page.) |
Other Data
| Transportation | Not dangerouse goods |
| Under the room temperature and away from light | |
| HS Code | 294200 |
| Storage | Under the room temperature and away from light |
| Shelf Life | 2 years |
| Market Price | USD 1500/kg |
| Use Pattern |
| TRIS(4-ETHOXYPHENYL)BISMUTH CAS#: 90591-48-3 is added to the fuel of rocket as cruing agent. |
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